If the girls had been on a standing train, the first girl's calculations would have been correct, but their train was moving. It took 5 minutes to meet a second train, but then it took the second train 5 more minutes to reach where the girls met the first train. So the time between trains is 10 minutes, not 5, and only 6 trains per hour arrive in the city.
Fire up your brain and see if you can remember your multiplication tables and more! See! There are reasons to use math outside of school!